Wilger, Dale J.’s team published research in Chemical Science in 4 | CAS: 5205-11-8

Chemical Science published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C8H10O2, Synthetic Route of 5205-11-8.

Wilger, Dale J. published the artcileCatalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system, Synthetic Route of 5205-11-8, the publication is Chemical Science (2013), 4(8), 3160-3165, database is CAplus.

Herein is presented a direct method for the metal-free hydrotrifluoromethylation of alkenes. The method relies on the single electron oxidation of a com. available sodium trifluoromethanesulfinate salt (CF3SO2Na, Langlois reagent) by N-Me-9-mesitylacridinium as a photoredox catalyst. Me thiosalicylate is used as a substoichiometric H-atom donor for aliphatic alkenes, and thiophenol is used as a stoichiometric H-atom donor for styrenyl substrates. The substrate scope for the transformation is broad, including mono-, di- and trisubstituted aliphatic and styrenyl alkenes, with high regioselectivity in nearly all cases examined

Chemical Science published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C8H10O2, Synthetic Route of 5205-11-8.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics