Calow, Adam D. J. published the artcileCarbonylative N-Heterocyclization via Nitrogen-Directed C-C Bond Activation of Nonactivated Cyclopropanes, Application of Dimethyl fumarate, the publication is Journal of the American Chemical Society (2022), 144(25), 11069-11074, database is CAplus and MEDLINE.
Under Rh-catalyzed conditions, secondary amines and anilines function as directing groups to facilitate regioselective C-C bond activation of nonactivated cyclopropanes. The resulting amino-stabilized rhodacycles underwent carbonylative C-N bond formation en route to challenging seven- and eight-membered lactams. The processes represented rare examples where C-C bond oxidative addition of nonactivated cyclopropanes is exploited in reaction design.
Journal of the American Chemical Society published new progress about 624-49-7. 624-49-7 belongs to esters-buliding-blocks, auxiliary class Inhibitor,Natural product, name is Dimethyl fumarate, and the molecular formula is C6H8O4, Application of Dimethyl fumarate.
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https://en.wikipedia.org/wiki/Ester,
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