Iron-catalyzed oxidative functionalization of C(sp3)-H bonds under bromide-synergized mild conditions was written by Yu, Han;Zhao, Qixin;Wei, Zheyu;Wu, Zhikang;Li, Qi;Han, Sheng;Wei, Yongge. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Computed Properties of C8H16O2 The following contents are mentioned in the article:
An efficient oxidation and functionalization of C-H bonds with an inorganic-ligand supported iron catalyst and hydrogen peroxide to prepare the corresponding ketones, e.g., 9H-fluoren-9-one was achieved using the bromide ion as a promoter. Preliminary mechanistic investigations indicated that the bromide ion can bind to FeMo6 to form a supramol. species (FeMo6.2Br), which can effectively catalyze the reaction. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Computed Properties of C8H16O2).
Methyl heptanoate (cas: 106-73-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Computed Properties of C8H16O2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics