Abraham model correlations for enthalpies of solvation of organic solutes dissolved in methyl acetate and octane was written by Lu, Jonathan Z.;Acree, William E. Jr.;Abraham, Michael H.. And the article was included in Physics and Chemistry of Liquids in 2020.Application of 106-73-0 The following contents are mentioned in the article:
Data have been assembled from the published literature on the enthalpies of solvation for 63 compounds dissolved in Me acetate and for 67 compounds dissolved in octane. It is shown that an Abraham solvation equation can successfully correlate the exptl. enthalpies of solvation in both Me acetate and octane to within standard deviations of 2.89 and 2.15 kJ mol-1, resp. The correlations determined in the present study provide very accurate math. descriptions of the measured enthalpy of solvation data at 298 K, which in the case of Me acetate span a range of about 110 kJ mol-1. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Application of 106-73-0).
Methyl heptanoate (cas: 106-73-0) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Application of 106-73-0
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics