Cobalt-catalysed selective synthesis of aldehydes and alcohols from esters was written by Pattanaik, Sandip;Gunanathan, Chidambaram. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020.Name: Methyl heptanoate The following contents are mentioned in the article:
Efficient and selective reduction of esters R1COOR2 (R1 = n-pentyl, Ph, 4-MeC6H4, etc.; R2 = Me, Et, n-Bu, Bn) to aldehydes R1CHO (R1 = Ph, 4-MeC6H4, Bn, etc.) and alcs. R1CH2OH (R1 = Ph, 4-FC6H4, 4-MeC6H4, etc.) is reported in which a simple cobalt pincer catalyst catalyzes both transformations using diethylsilane as a reductant. Remarkably, the reaction selectivity is controlled by the stoichiometry of diethylsilane. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Name: Methyl heptanoate).
Methyl heptanoate (cas: 106-73-0) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Name: Methyl heptanoate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics