Nucleophilic Substitutions of Alcohols in High Levels of Catalytic Efficiency was written by Stach, Tanja;Draeger, Julia;Huy, Peter H.. And the article was included in Organic Letters in 2018.SDS of cas: 5444-75-7 The following contents are mentioned in the article:
A practical method for the nucleophilic substitution (SN) of alcs. furnishing alkyl chlorides, bromides, and iodides under stereochem. inversion in high catalytic efficacy is introduced. The fusion of diethylcyclopropenone as a simple Lewis base organocatalyst and benzoyl chloride as a reagent allows notable turnover numbers up to 100. Moreover, the use of plain acetyl chloride as a stoichiometric promotor in an invertive SN-type transformation is demonstrated for the first time. The operationally straightforward protocol exhibits high levels of stereoselectivity and scalability and tolerates a variety of functional groups. This study involved multiple reactions and reactants, such as 2-Ethylhexyl benzoate (cas: 5444-75-7SDS of cas: 5444-75-7).
2-Ethylhexyl benzoate (cas: 5444-75-7) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.SDS of cas: 5444-75-7
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics