Synthesis and Biochemical Evaluation of an Artificial, Fluorescent Glucosinolate (GSL) was written by Glindemann, Carina Patrizia;Backenkoehler, Anita;Strieker, Matthias;Wittstock, Ute;Klahn, Philipp. And the article was included in ChemBioChem in 2019.Reference of 604-69-3 The following contents are mentioned in the article:
The synthesis of the first example of a fluorescent glucosinolate (GSL)-BODIPY conjugate based on an azide-containing artificial GSL precursor (GSL-N3) is reported. Biochem. evaluation of the artificial GSLs revealed that the compounds are converted to the corresponding isothiocyanates in the presence of myrosinase. Furthermore, myrosinase-catalyzed hydrolysis in the presence of plant specifier proteins yielded the expected alternative products, namely nitriles. The easy assembly of the fluorescent GSL-BODIPY conjugate by click chem. from GSL-N3 holds potential for application as a fluorescence labeling tool to investigate GSL-associated processes. This study involved multiple reactions and reactants, such as (2S,3R,4S,5R,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate (cas: 604-69-3Reference of 604-69-3).
(2S,3R,4S,5R,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate (cas: 604-69-3) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Reference of 604-69-3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics