Regio- and enantioselective functionalization of acyclic polyprenoids was written by Barrero, Alejandro F.;Quilez del Moral, Jose F.;Herrador, Maria del Mar;Sanchez, Elena M.;Arteaga, Jesus F.. And the article was included in Journal of the Mexican Chemical Society in 2006.Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate The following contents are mentioned in the article:
Results obtained in the positional selective functionalization of the double bond located at the terminal isopropylidene unit of acyclic polyprenoids were presented. Studies were undertaken to introduce hydroxyl or related oxygenated functions using oxidation with SeO2 or catalytic procedures employing Pd(II) catalysts. This functionalization is found in many natural or synthetic acyclic terpenes and would permit subsequent regio- and stereoselective epoxidation reactions. Furthermore, the asym. dihydroxylation procedure was optimized using various polyprenoids in order to generalize this methodol. as the key step for the enantioselective synthesis of epoxides. This study involved multiple reactions and reactants, such as (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate).
(2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate (cas: 37905-02-5) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Recommanded Product: (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics