Qiu, Nannan published the artcileA photo- and thermo-responsive star-shaped diblock copolymer with a porphyrin core prepared via consecutive ATRPs, Safety of 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, the publication is RSC Advances (2016), 6(53), 47912-47918, database is CAplus.
A star-shaped and diblock copolymer poly(6-[4-(4-methoxyphenylazo)phenoxy]hexylmethacrylate)s-b-poly(N-isopropylacrylamide)s with a zinc-porphyrin core (PAzo-b-PNIPAM) is synthesized via consecutive atom transfer radical polymerizations (ATRPs). The synthesis involves the preparation of the intermediate poly(6-[4-(4-methoxyphenylazo)phenoxy]hexylmethacrylate) with a zinc-porphyrin core (por-PAzo) via ATRP, and then por-PAzo is used as a macroinitiator to polymerize N-isopropylacrylamide (NIPAM) via ATRP to gain PAzo-b-PNIPAM. The structures of the target products are characterized by FT-IR, 1H NMR and UV-vis spectra, and the polydispersity index (PDI) indicates that the mol. weight distribution is narrow and the polymerization is well controlled. Furthermore, the photo- and thermo-responsive properties are also investigated in detail, which demonstrate that the star-shaped diblock copolymer PAzo-b-PNIPAM has a potential application in targeted photodynamic therapy and photo-electro informational storage.
RSC Advances published new progress about 135529-02-1. 135529-02-1 belongs to esters-buliding-blocks, auxiliary class azo,Alkenyl,Benzene,Ester,Ether, name is 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate, and the molecular formula is C23H28N2O4, Safety of 6-(4-((4-Methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate.
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https://en.wikipedia.org/wiki/Ester,
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