Noji, Masahiro published the artcileProton-accelerated Lewis acid catalysis for stereo- and regioselective isomerization of epoxides to allylic alcohols, Recommanded Product: 3-Methylbut-2-en-1-yl benzoate, the publication is Chemical Communications (Cambridge, United Kingdom) (2021), 57(58), 7104-7107, database is CAplus and MEDLINE.
The isomerization of epoxides to allylic alcs. was developed via proton-accelerated Lewis acid catalysis. The addition of tBuOH as a proton source was the key to the efficient catalytic cycle. Trisubstituted epoxides, including enantioenriched derivatives, were selectively converted to secondary-allylic alcs. without loss of enantiopurity.
Chemical Communications (Cambridge, United Kingdom) published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H14O2, Recommanded Product: 3-Methylbut-2-en-1-yl benzoate.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics