A novel column modification approach for capillary gas chromatography: combination with a triptycene-based stationary phase achieves high separation performance and inertness was written by He, Yongrui;Qi, Meiling. And the article was included in New Journal of Chemistry in 2021.Application In Synthesis of Methyl heptanoate The following contents are mentioned in the article:
This work presents a novel strategy for the construction of a capillary column with high resolving performance and inertness for gas chromatog. (GC) anal. by combining the proposed surface modification with a selective stationary phase. Through the modified biphasic sol-gel reaction inside a capillary GC column, porous modification was made on the capillary surface (PM capillary) prior to coating with a stationary phase. Herein, we designed and synthesized a new triptycene-based stationary phase (TPPG) for the study. Using the proposed strategy, the PM-TPPG column was fabricated with a column efficiency of 4950 plates per m determined by n-dodecane at 120°C and then investigated for its separation performance, inertness, repeatability, loadability and thermal stability. As demonstrated, the PM-TPPG column showed distinct advantages in these aspects over two reference columns (TPPG column and com. PEG column). Particularly, the PM-TPPG column well resolved all the components in the Grob mixture and exhibited distinctly improved peak shapes for carboxylic acids and heterocyclic bases. Moreover, it exhibited excellent repeatability and reproducibility and higher column loadability than the two reference columns. Its applications to purity monitoring of chem. products demonstrate its good potential for practical GC anal. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Application In Synthesis of Methyl heptanoate).
Methyl heptanoate (cas: 106-73-0) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Application In Synthesis of Methyl heptanoate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics