The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 124-06-1, Name is Ethyl tetradecanoate, SMILES is CCCCCCCCCCCCCC(OCC)=O, in an article , author is Wheatley, Emilie, once mentioned of 124-06-1, Name: Ethyl tetradecanoate.
Diastereo-, Enantio-, and anti-Selective Formation of Secondary Alcohol and Quaternary Carbon Stereocenters by Cu-Catalyzed Additions of B-Substituted Allyl Nucleophiles to Carbonyls
A general method for the synthesis of secondary homoallylic alcohols containing alpha-quaternary carbon stereogenic centers in high diastereo- and enantioselectivity (up to >20:1 dr and >99:1 er) is disclosed. Transformations employ readily accessible aldehydes, allylic diboronates, and a chiral copper catalyst and proceed by gamma-addition of in situ generated enantioenriched boron-stabilized allylic copper nucleo-philes. The catalytic protocol is general for a wide variety of aldehydes as well as a variety of 1,1-allylic diboronic esters. Hammett studies disclose that diastereoselectivity of the reaction is correlated to the electronic nature of the aldehyde, with dr increasing as aldehydes become more electron poor.
Interested yet? Read on for other articles about 124-06-1, you can contact me at any time and look forward to more communication. Name: Ethyl tetradecanoate.