Kumar, Kamlesh et al. published their research in Polyhedron in 2017 | CAS: 106-73-0

Methyl heptanoate (cas: 106-73-0) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is 纬-valerolactone.Quality Control of Methyl heptanoate

Palladium(II) complexes bearing mixed N^N^X (X = O and S) tridentate ligands as pre-catalysts for the methoxycarbonylation of selected 1-alkenes was written by Kumar, Kamlesh;Darkwa, James. And the article was included in Polyhedron in 2017.Quality Control of Methyl heptanoate The following contents are mentioned in the article:

The methoxycarbonylation of selected 1-alkenes catalyzed by various neutral and cationic palladium(II) complexes, containing mixed N^N^X (X = O and S) tridentate ligands 2-[(3,5-dimethyl-1H-pyrazol-1-yl)methyl]-6-(phenoxymethyl)pyridine (L1), 2-[(3,5-di-tert-butyl-1H-pyrazol-1-yl)methyl]-6-(phenoxymethyl)pyridine (L2), 2-[(3,5-dimethyl-1H-pyrazol-1-yl)methyl]-6-(phenylthiomethyl)pyridine (L3), 2-[(3,5-di-tert-butyl-1H-pyrazol-1-yl)methyl]-6-(phenylthiomethyl)pyridine (L4), has been investigated. Neutral complexes, [(k2-L1)Pd(CH3)(Cl)] (1a), [(k2-L2)Pd(CH3)(Cl)] (2a), [(k2-L3)Pd(CH3)(Cl)] (3a), [(k2-L4)Pd(CH3)(Cl)] (4a), and the salts, [(k3-L3)Pd(CH3)][BArF4] (3c) and [(k3-L4)Pd(CH3)][BArF4] (4c), underwent complete decomposition during the reaction to palladium black and showed no catalytic activity. However, the addition of PPh3 to the reaction dramatically increased the catalytic activity. On the other hand, the salts, [(k2-L1)Pd(CH3)(PPh3)][BArF4] (1b), [(k2-L2)Pd(CH3)(PPh3)][BArF4] (2b), [(k2-L3)Pd(CH3)(PPh3)][BArF4] (3b) and [(k2-L4)Pd(CH3)(PPh3)][BArF4] (4b), showed good conversion of the selected olefins to branched and linear esters without PPh3. Addition of PPh3 to reactions with 1b–4b significantly improved catalytic activity. All decomposition of complexes led to the formation of the known palladium complexes, [Pd(PPh3)2(Cl)(CH3)] and [Pd(PPh3)2Cl2]. The decomposition of all palladium complexes could be followed by NMR studies and [Pd(PPh3)2Cl2] could be isolated from the crude methoxycarbonylation reaction. This study involved multiple reactions and reactants, such as Methyl heptanoate (cas: 106-73-0Quality Control of Methyl heptanoate).

Methyl heptanoate (cas: 106-73-0) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Cyclic esters are called lactones, regardless of whether they are derived from an organic or inorganic acid. One example of an organic lactone is 纬-valerolactone.Quality Control of Methyl heptanoate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics