Recommanded Product: Benzyl acrylateIn 2020 ,ãAtroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C-H Functionalization Strategyã?was published in Chem. The article was written by Jin, Liang; Yao, Qi-Jun; Xie, Pei-Pei; Li, Ya; Zhan, Bei-Bei; Han, Ye-Qiang; Hong, Xin; Shi, Bing-Feng. The article contains the following contents:
The highly atroposelective synthesis of axially chiral styrenes with an open-chained alkenes via a C-H functionalization strategy is reported. Various axially chiral styrenes were produced by Pd(II)-catalyzed C-H alkenylation and alkynylation in good yields (up to 99%) and enantioselectivities (up to 99% ee) by using L-pyroglutamic acid as an inexpensive chiral ligand. The potential application of the styrene atropisomers was demonstrated by a Co(III)-catalyzed enantioselective C-H amidation of ferrocene with axially chiral styrene-type acid as a chiral ligand. Exptl. and computational studies were conducted to elucidate the reaction mechanism. The chiral induction model of the enantioselectivity-determining C-H bond activation step was also provided based on DFT calculations The experimental process involved the reaction of Benzyl acrylate(cas: 2495-35-4Recommanded Product: Benzyl acrylate)
Benzyl acrylate(cas: 2495-35-4) is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid, a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.Recommanded Product: Benzyl acrylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics