Reference of 3-(Methoxycarbonyl)benzoic acidOn September 27, 2019 ,《Synthesis of Biaryls via Decarbonylative Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of Carboxylic Acids》 was published in iScience. The article was written by Liu, Chengwei; Ji, Chong-Lei; Qin, Zhi-Xin; Hong, Xin; Szostak, Michal. The article contains the following contents:
The present report implements a decarbonylative version with loss of carbon monoxide (CO) that enables to directly engage acids ArC(O)OH (Ar1 = 2-[(E)-2-phenylethenyl]phenyl, naphthalen-1-yl, pyridin-3-yl, etc.)/Ar1B(OH)2 (Ar1 = thiophen-3-yl, naphthalen-2-yl, 2H-1,3-benzodioxol-5-yl, etc.) in a Suzuki-Miyaura cross-coupling to produce biaryls as a general method with high cross-coupling selectivity using a well-defined Pd(0)/(II) catalytic cycle. This protocol shows a remarkably broad scope (>80 examples) and is performed in the absence of exogenous inorganic bases. In a broader context, the approach shows promise for routine applications in the synthesis of biaryls Ar-Ar1 by carefully controlled decarbonylation of prevalent acids. In addition to this study using 3-(Methoxycarbonyl)benzoic acid, there are many other studies that have used 3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0Reference of 3-(Methoxycarbonyl)benzoic acid) was used in this study.
3-(Methoxycarbonyl)benzoic acid(cas: 1877-71-0) belongs to esters. They are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils.Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones.Reference of 3-(Methoxycarbonyl)benzoic acid
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics