The author of 《An electrochemical off-on method for pyrimidin-2(1H)-one synthesis via three-component cyclization》 were Kong, Yanyan; Li, Yabo; Huang, Mengmeng; Kim, Jung Keun; Wu, Yangjie. And the article was published in Green Chemistry in 2019. Category: esters-buliding-blocks The author mentioned the following in the article:
A green and simple ‘one-pot’ electrochem. off-on approach to synthesize pyrimidin-2(1H)-ones was realized without any catalyst, oxidant and toxic reagent. The desired products were obtained in moderate to good yields after the stepwise ‘one-pot’ reaction. The results of control experiments and cyclic voltammetry indicated that the electrooxidation of DHPMs might proceed via two steps process losing two-electrons and two-protons by absorption control with radical intermediates.Methyl 3-oxovalerate(cas: 30414-53-0Category: esters-buliding-blocks) was used in this study.
Methyl 3-oxovalerate(cas: 30414-53-0) belongs to ketone compounds. Ketone compounds have important physiological properties. They are found in several sugars and in compounds for medicinal use, including natural and synthetic steroid hormones. Molecules of the anti-inflammatory agent cortisone contain three ketone groups.Category: esters-buliding-blocks
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics