《A heterogeneous and recoverable palladium catalyst to access the regioselective C-H alkenylation of quinoline N-oxides》 was published in Green Chemistry in 2020. These research results belong to Sciosci, Daniele; Valentini, Federica; Ferlin, Francesco; Chen, Shaomin; Gu, Yanlong; Piermatti, Oriana; Vaccaro, Luigi. COA of Formula: C10H10O2 The article mentions the following:
Herein, the first C-2-selective C-H alkenylation of quinoline N-oxides catalyzed using a heterogeneous palladium catalyst is disclosed. The protocol does not require the use of an external oxidant and it is applicable to an ample substrate scope always showing excellent site selectivity. This process is made accessible by the use of a specific 1,2,3-triazolium-tagged heterogeneous polymeric catalytic system. The catalyst can be efficiently recovered and reused with no decrease of its catalytic performance and hot filtration and mercury poisoning tests suggest that its mechanism of action is operatively heterogeneous. In addition, mechanistic studies revealed that C-H activation reaction pathways are operative, setting the stage for the direct synthesis of 2-functionalized quinolines using N-oxide functionality as both a directing group and an oxidant. In the experimental materials used by the author, we found Benzyl acrylate(cas: 2495-35-4COA of Formula: C10H10O2)
Benzyl acrylate(cas: 2495-35-4) has been used in preparation of high refractive index polyacrylates. Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.COA of Formula: C10H10O2
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