Chen, Zhi-Min; Liu, Jianbo; Guo, Jing-Yao; Loch, Maximillan; DeLuca, Ryan J.; Sigman, Matthew S. published an article in 2019, the title of the article was Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives.Product Details of 10472-24-9 And the article contains the following content:
A regioselective and enantioselective palladium-catalyzed relay Heck alkenylation of alkenylbenzene derivatives to construct remote stereocenters was disclosed. Various β-substituted styrenes were readily obtained in moderate yields with good to excellent levels of enantioselectivity. This strategy provided rapid access to enantioenriched δ, ε, ζ and η-alkenyl aryl compounds from simple starting materials. Mechanistic studies suggested that termination of the relay reaction was controlled by affinity of the arene for the Pd complex during migration. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Product Details of 10472-24-9
The Article related to alkenylarene alkenyl triflate palladium catalyst regioselective enantioselective heck reaction, Alicyclic Compounds: Cyclohexanes and other aspects.Product Details of 10472-24-9
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