Gavel, Marine et al. published their research in Organic Letters in 2019 |CAS: 2873-29-2

The Article related to alc preparation, acetate deprotection zirconium hydride dibalh deacetylation, General Organic Chemistry: Synthetic Methods and other aspects.Related Products of 2873-29-2

On April 5, 2019, Gavel, Marine; Courant, Thibaut; Joosten, Antoine Yvan Philippe; Lecourt, Thomas published an article.Related Products of 2873-29-2 The title of the article was Regio- and Chemoselective Deprotection of Primary Acetates by Zirconium Hydrides. And the article contained the following:

A combination of DIBAL-H and Cp2ZrCl2 is shown to promote the regioselective cleavage of primary acetates on a broad scope of substrates, ranging from carbohydrates to terpene derivatives, with a high tolerance toward protecting groups and numerous functionalities found in natural products and bioactive compounds Apart from providing highly valuable building blocks in only two steps from biosourced raw materials, this selective de-O-acetylation should also be strongly helpful to solve selectivity issues in organic synthesis. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).Related Products of 2873-29-2

The Article related to alc preparation, acetate deprotection zirconium hydride dibalh deacetylation, General Organic Chemistry: Synthetic Methods and other aspects.Related Products of 2873-29-2

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics