On May 1, 2015, Zhang, Xiaomin; Wang, Jian; Wan, Zehong published an article.Reference of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate The title of the article was New Reagent for Highly Efficient Synthesis of Trifluoromethyl-Substituted Arenes and Heteroarenes. And the article contained the following:
A new reagent trimethylsilyl chlorodifluoroacetate (TCDA) is reported for the introduction of a -CF3 group to arenes and heteroarenes. Compared with current known reagents, TCDA shows very broad scope with respect to electron-deficient, -neutral, and -rich aryl/heteroaryl iodides as well as excellent functional group tolerance, including ester, amide, aldehyde, hydroxyl, and carboxylic acid. The experimental process involved the reaction of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate(cas: 141940-37-6).Reference of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate
The Article related to trifluoromethylation aryl heteroaryl iodide trimethylsilyl chlorodifluoroacetate, General Organic Chemistry: Synthetic Methods and other aspects.Reference of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate
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