On September 6, 2019, Fan, Lian-Feng; Wang, Pu-Sheng; Gong, Liu-Zhu published an article.SDS of cas: 10472-24-9 The title of the article was Monodentate Phosphorus Ligand-Enabled General Palladium-Catalyzed Allylic C-H Alkylation of Terminal Alkenes. And the article contained the following:
Monodentate phosphorus ligands have been found to enable the palladium-catalyzed allylic C-H alkylation reaction of terminal alkenes with a wide variety of carbon nucleophiles. Moreover, an asym. allylic C-H alkylation of terminal alkenes with pyrazol-5-ones has been established in the presence of chiral phosphoramidite ligand and chiral phosphoric acid as co-catalyst. Mechanistic studies suggest that a ternary Pd(0) complex, coordinated with a monodentate phosphorus ligand, benzoquinone, and alkene, is most likely to be an active species. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).SDS of cas: 10472-24-9
The Article related to monodentate phosphorus ligand palladium catalyst allylic alkylation terminal alkene, regioselective stereoselective allylic alkylation, General Organic Chemistry: Synthetic Methods and other aspects.SDS of cas: 10472-24-9
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