Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 5445-17-0, Name is Methyl 2-bromopropanoate, SMILES is CC(C(OC)=O)Br, belongs to esters-buliding-blocks compound. In a document, author is Yang, Shuang, introduce the new discover, Product Details of 5445-17-0.
Divergent synthesis of oxazolidines and morpholines via PhI(OAc)(2)-mediated difunctionalization of alkenes
Herein we describe the PhI(OAc)(2)-mediated 1,1- and 1,2-difunctionalization of alkenes with N-tosyl amino alcohols to form oxazolidine and morpholine derivatives. This transformation was realized under mild reaction conditions and allows application to various substrates furnishing the multi-substituted oxazolidines and morpholines with yields up to 98%. A deuterium-labeling experiment was carried out and the result indicated that a phenyl group migration occurred to generate oxazolidine products.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 5445-17-0 is helpful to your research. Product Details of 5445-17-0.