Yuan, Zaifeng; Zhu, Chunyu; Ma, Zhixian; Xia, Chengfeng published an article in 2018, the title of the article was Copper-catalyzed amination of an α-C(sp3)-H bond in inactivated ethers to synthesize α-aminonitriles.Quality Control of Methyl N-Methylanthranilate And the article contains the following content:
A copper-catalyzed functionalization of inert cyclic ethers was developed to provide α-aminonitriles via a cascade oxidation/amination/ring-opening/cyanation reaction. A series of highly versatile α-aminonitriles were obtained from primary or secondary anilines, and heterocyclic and aliphatic amines with high yields. This process features excellent functional group tolerance, a broad substrate scope, and high activity under ambient conditions. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Quality Control of Methyl N-Methylanthranilate
The Article related to aminonitrile preparation, ether amine cyanide amination copper catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Nitriles, Isonitriles, and Acyl Cyanides and other aspects.Quality Control of Methyl N-Methylanthranilate
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