Application of 111-82-0, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 111-82-0, Name is Methyl laurate, SMILES is CCCCCCCCCCCC(OC)=O, belongs to esters-buliding-blocks compound. In a article, author is Yang, Yuhuan, introduce new discover of the category.
Iridium-Catalyzed Enantioselective Unbiased Methylene C(sp(3))-H Borylation of Acyclic Amides
We herein report amide directed enantioselective beta-C(sp(3))-H borylation of unbiased methylene C-H bonds of acyclic amides enabled by iridium catalysis for the first time. The key to the success of this transformation relies on the careful selection of the combination of iridium precursor and chiral bidentate boryl ligands. A variety of functional groups are well-tolerated, affording chiral beta-functionalized amides in good to excellent enantioselectivities. We also demonstrate the application of the current method by stereospecific conversion of C-B bond into other functionalities.
Application of 111-82-0, One of the oldest and most widely used commercial enzyme inhibitors is aspirin, which selectively inhibits one of the enzymes involved in the synthesis of molecules that trigger inflammation. you can also check out more blogs about 111-82-0.