On October 5, 2013, Osawa, Tsutomu; Kizawa, Tomoko; Ikeda, Shinji; Kitamura, Takayuki; Inoue, Yoshihisa; Borovkov, Victor published an article.Application In Synthesis of (R)-Methyl 3-hydroxybutanoate The title of the article was Heterogeneous enantioselective hydrogenation: pH dependence and interplay between catalytic efficacy and surface composition. And the article contained the following:
The performance of a catalytic system consisting of metallic Ni powder, tartaric acid (TA), and NaBr in the enantioselective hydrogenation of Me acetoacetate was strongly influenced by the pH of TA solution upon chiral modification, which is attributable to the pH-induced change in the surface composition of Ni catalyst as unambiguously confirmed by XPS for the first time. The experimental process involved the reaction of (R)-Methyl 3-hydroxybutanoate(cas: 3976-69-0).Application In Synthesis of (R)-Methyl 3-hydroxybutanoate
The Article related to acetoacetate enantioselective hydrogenation chiral modified nickel catalyst, butyrate hydroxy asym synthesis, nickel tartaric acid catalyst asym hydrogenation ph dependence and other aspects.Application In Synthesis of (R)-Methyl 3-hydroxybutanoate
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