On August 15, 2020, Guo, Yujing; Pei, Chao; Koenigs, Rene M. published an article.Product Details of 2873-29-2 The title of the article was Substrate-Controlled Cyclopropanation Reactions of Glycals with Aryl Diazoacetates. And the article contained the following:
Cyclopropanation reactions of D-glucal and D-galactal derivatives with aryldiazoacetates can be conducted in a substrate-controlled, stereoselective fashion using simple Rh(II) catalysts, which is further supported by DFT studies. Following this methodol., sugar-derived, donor-acceptor cyclopropanes can be accessed that allow stereoselective O-glycosylation reactions. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).Product Details of 2873-29-2
The Article related to transition state cyclopropanation glucal diazoalkane dft aryl diazoacetate, rhodium catalyst cyclopropane stereoselective glycosylation glycoside carboxylate preparation, stereoselective glycosylation cyclopropanation galactal aryldiazoacetate glucal catalyst and other aspects.Product Details of 2873-29-2
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