Wang, Qiang; Tang, Xiang-Ying; Shi, Min published the artcile< Metal-Free Cross-Coupling of Arylboronic Acids and Derivatives with DAST-Type Reagents for Direct Access to Diverse Aromatic Sulfinamides and Sulfonamides>, Reference of 112-63-0, the main research area is aromatic sulfinamide sulfonamide preparation; arylboronic acid ester aminosulfur trifluoride cross coupling; arylboronic acids; cross-coupling; sulfinamides; sulfonamides; synthetic methods.
We have developed a simple and convenient method for the cross-coupling of arylboronic acids and their derivatives with DAST-type reagents under mild and metal-free conditions to directly afford sulfinamides in moderate to good yields. Moreover, sulfonamides were obtained after a simple oxidation reaction. The reaction mechanism was investigated by 18O-labeling experiments, and the synthetic utility was demonstrated by the sulfoxidation of natural products.
Angewandte Chemie, International Edition published new progress about Arenesulfonamides Role: SPN (Synthetic Preparation), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Reference of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics