Ghaffari, Behnaz; Preshlock, Sean M.; Plattner, Donald L.; Staples, Richard J.; Maligres, Peter E.; Krska, Shane W.; Maleczka, Robert E.; Smith, Milton R. published the artcile< Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis>, Related Products of 112-63-0, the main research area is ortho silylphosphinylbenzene tethered iridium cyclooctadiene preparation catalyst orthoborylation; crystal structure ortho silylphosphinylbenzene tethered iridium cyclooctadiene; mol structure ortho silylphosphinylbenzene tethered iridium cyclooctadiene.
Ir catalysts supported by ortho-(diisopropylsilyl)(di-p-tolylphosphino)benzene bidentate ligand that contains P- or N-donors, effects ortho-borylations for a range of substituted aromatics E.g., reaction of C6H5CO2Me with bis(pinacolato)diboron (B2pin2) in the presence of 1.25 mol% [Ir(OMe)(cod)]2/ 2.5 mol% (p-tol)2PC6H4-2-(SiHiPr2) in THF at 80° to give 72% yield of Me 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.
Journal of the American Chemical Society published new progress about Amides Role: RCT (Reactant), RACT (Reactant or Reagent) (benzamides). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Related Products of 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics