Molle, Edgar; Mutlu, Hatice; Theato, Patrick published the artcile< Synthesis and Post-Polymerization Modification of Poly(N-(4-Vinylphenyl)Sulfonamide)s>, Name: Perfluorophenyl acrylate, the main research area is polyvinylphenylsulfonamide post modification acrylate aza Michael reaction; free radical polymerization; post-polymerization modification; sulfonamide-based polymers; β-amino acids.
Herein, a straightforward synthesis of a novel class of polymers, i.e., poly(N-(4-vinylphenyl)sulfonamide)s, and their monomers is reported. A set of monomers with varying electron densities, fine-tuned by different substituents on the aromatic sulfonamide moiety, is polymerized by free radical polymerization featuring low molar masses (2300 ≤ Mn ≤ 3200 g mol-1) and low dispersities (1.15 ≤ Dj ≤ 1.47). Further, the post-polymerization modification of the obtained polymers via aza-Michael addition with electron-deficient alkenes is demonstrated using organic superbases as catalysts, paving the way toward the facile synthesis of novel polymeric protected β-amino acid derivatives
Macromolecular Rapid Communications published new progress about Arenesulfonamides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 71195-85-2 belongs to class esters-buliding-blocks, and the molecular formula is C9H3F5O2, Name: Perfluorophenyl acrylate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics