Alazet, Sebastien; Le Vaillant, Franck; Nicolai, Stefano; Courant, Thibaut; Waser, Jerome published the artcile< Divergent Access to (1,1) and (1,2)-Azidolactones from Alkenes using Hypervalent Iodine Reagents>, SDS of cas: 112-63-0, the main research area is azidolactone preparation; alkene carboxylic acid cyclic hypervalent iodine azidation cyclization; 1,2 shift; azides; hypervalent iodine; lactones; photoredox.
A versatile synthesis of azidolactones, e.g., I through azidation and cyclization of carboxylic acids onto alkenes, e.g., 2-(1-phenylvinyl)benzoic acid has been developed. Based on either photoredox or palladium catalysis, (1,1) and (1,2) azido lactones can be selectively synthesized. The choice of catalyst and benziodoxol(on)e reagent serving as azide source was essential to initiate either a radical or Lewis acid mediated process with divergent outcome. These transformations were carried out under mild conditions using low catalyst loading and gave access to a large scope of azido lactones.
Chemistry – A European Journal published new progress about Alkenes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, SDS of cas: 112-63-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics