Orbegozo, Thomas’s team published research in European Journal of Organic Chemistry in 2010-06-30 | 112-63-0

European Journal of Organic Chemistry published new progress about Aldehydes Role: BPN (Biosynthetic Preparation), BIOL (Biological Study), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.

Orbegozo, Thomas; de Vries, Johannes G.; Kroutil, Wolfgang published the artcile< Biooxidation of Primary Alcohols to Aldehydes through Hydrogen Transfer Employing Janibacter terrae>, COA of Formula: C19H34O2, the main research area is Janibacter oxidation primary alc.

Chemoselective oxidations still represent a challenge for chemists. Lyophilized cells of Janibacter terrae were employed for the chemoselective oxidation of primary alcs. to the corresponding aldehydes by hydrogen transfer with the use of acetaldehyde as the hydrogen acceptor. Secondary alc. moieties were transformed at a much slower rate. The substrate spectrum encompasses substituted benzyl alcs., whereby substrates with a substituent in the meta position were well tolerated, whereas only very small substituents were tolerated in the ortho position. Furthermore, n-alkanols and allylic alcs. were transformed with good conversions. The biocatalyst was compatible with DMSO as a water miscible organic solvent up to 30 % volume/volume

European Journal of Organic Chemistry published new progress about Aldehydes Role: BPN (Biosynthetic Preparation), BIOL (Biological Study), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, COA of Formula: C19H34O2.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics