Reid, Margaret D.; Tirado, Liz; Zhang, Jianwei; Dike, Nwamara; Herndon, James W. published the artcile< Reaction of cyclopropylcarbene-metal complexes with nucleophiles, halogens and HX>, Name: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is cyclopropyl chromium carbene complex preparation reaction nucleophile halogen pseudohalogen; chromium cyclopropyl phenylthio carbene complex preparation reaction nucleophile halogen; dihalo thiophenyl butene preparation stereocontrol.
The reaction of halogens, pseudohalogens, and HX with cyclopropyl(phenylthio)carbene-chromium complexes leads to the formation of 1,4-dihalo-1-thiophenyl-1-butene systems with a moderate-high degree of stereocontrol in the formation of the alkene. A mechanism involving electrophilic activation of the carbene complex followed by nucleophilic attack at the cyclopropane carbon has been proposed.
Journal of Organometallic Chemistry published new progress about Alkenes Role: SPN (Synthetic Preparation), PREP (Preparation). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Name: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics