Ester is a chemical compound derived from an oxoacid (organic or inorganic) in which at least one –OH hydroxyl group is replaced by an –O– alkyl (alkoxy) group, 870-50-8, formula is C10H18N2O4, Name is Di-tert-butyl diazene-1,2-dicarboxylate. as in the substitution reaction of a carboxylic acid and an alcohol. Safety of Di-tert-butyl diazene-1,2-dicarboxylate.
Xie, Pan;Shi, Sanshan;Hu, Xueqing;Xue, Cheng;Du, Dongdong research published 《 Sunlight Photocatalytic Synthesis of Aryl Hydrazides by Decatungstate-Promoted Acylation under Room Temperature》, the research content is summarized as follows. A sunlight photocatalytic synthesis of aryl hydrazides RC(O)N(Boc)NHBoc (R = 2-methylphenyl, 4-bromophenyl, naphthalen-2-yl, etc.) was achieved via a decatungstate-promoted addition process of aromatic aldehydes RCHO to di-tert-Bu azodicarboxylate. Aryl hydrazides can be produced in good to excellent yields under room temperature, even if the reaction was carried out as ”window ledge” mode. This process is easy to be operated and no addnl. additives are needed, which makes the practicability and application value increase obviously.
870-50-8, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., Safety of Di-tert-butyl diazene-1,2-dicarboxylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics