《Visible-light mediated tryptophan modification in oligopeptides employing acylsilanes》 was written by Reimler, Jannik; Studer, Armido. Name: H-Trp-OMe.HCl And the article was included in Chemistry – A European Journal in 2021. The article conveys some information:
A method for the selective tryptophan modification and labeling of tryptophan-containing peptides is described. Photoirradiation of acylsilanes generates reactive siloxycarbenes which undergo H-N-insertion into the indole moiety of tryptophan to give stable silyl protected hemiaminals. This method is successfully applied to chem. modify various tryptophan containing oligopeptides. The method enables the selective introduction of alkynes to peptides that are eligible for further alkyne-azide click chem. In addition, the dansyl fluorophore can be conjugated to a peptide using this approach. The results came from multiple reactions, including the reaction of H-Trp-OMe.HCl(cas: 7524-52-9Name: H-Trp-OMe.HCl)
H-Trp-OMe.HCl(cas:7524-52-9) is one of amino acid derivatives. Amino acid derivatives represent an important category of skin penetration promoters. These compounds possess hydrophobic chains attached to an amino acid headgroup via a biodegradable ester bond. Due to the amphiphilic nature of these derivatives, it is possible for them to enter into the SC lipid barrier and significantly disorganize skin membrane lipids.Name: H-Trp-OMe.HCl
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