Electric Literature of C3H2O3In 2020 ,《Spectral deconvolution in electrophoretic NMR to investigate the migration of neutral molecules in electrolytes》 was published in Magnetic Resonance in Chemistry. The article was written by Schmidt, Florian; Pugliese, Andrea; Santini, Catherine C.; Castiglione, Franca; Schoenhoff, Monika. The article contains the following contents:
Electrophoretic NMR (eNMR) is a powerful tool in studies of nonaqueous electrolytes, such as ionic liquids It delivers electrophoretic mobilities of the ionic constituents and thus sheds light on ion correlations. In applications of liquid electrolytes, uncharged additives are often employed, detectable via 1H NMR. Characterizing their mobility and coordination to charged entities is desirable; however, it is often hampered by small intensities and 1H signals overlapping with major constituents of the electrolyte. In this work, we evaluate methods of phase anal. of overlapping resonances to yield electrophoretic mobilities even for minor constituents. We use phase-sensitive spectral deconvolution via a set of Lorentz distributions for the investigation of the migration behavior of additives in two different ionic liquid-based lithium salt electrolytes. For vinylene carbonate as an additive, no field-induced drift is observed; thus, its coordination to the Li+ ion does not induce a correlated drift with Li+. On the other hand, in a solvate ionic liquid with tetraglyme (G4) as an additive, a correlated migration of tetraglyme with lithium as a complex solvate cation is directly proven by eNMR. The phase evaluation procedure of superimposed resonances thus broadens the applicability of eNMR to application-relevant complex electrolyte mixtures containing neutral additives with superimposed resonances. The experimental process involved the reaction of Vinylene carbonate(cas: 872-36-6Electric Literature of C3H2O3)
Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Electric Literature of C3H2O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics