Hyodo, Isao; Tobisu, Mamoru; Chatani, Naoto published the artcile< Catalytic Arylation of a C-H Bond in Pyridine and Related Six-Membered N-Heteroarenes Using Organozinc Reagents>, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate, the main research area is nitrogen heteroarene diphenylzinc direct arylation nickel; aryl nitrogen heteroarene preparation; nickel direct arylation catalyst.
Despite significant advances in the catalytic direct arylation of heteroarenes, the application of this reaction to pyridines has been met with limited success. An oxidative nucleophilic arylation strategy has been developed to overcome this problem. Pyridine, pyrazine, quinolone, and related electron-deficient N-heteroarenes can be arylated at the most electrophilic site using the developed nickel-catalyzed reaction. This protocol serves as a complementary method to catalytic direct arylation reactions.
Chemistry – An Asian Journal published new progress about Arylation. 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Recommanded Product: (9Z,12Z)-Methyl octadeca-9,12-dienoate.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics