《Distal γ-C(sp3)-H Olefination of Ketone Derivatives and Free Carboxylic Acids》 was published in Angewandte Chemie, International Edition in 2020. These research results belong to Park, Han Seul; Fan, Zhoulong; Zhu, Ru-Yi; Yu, Jin-Quan. COA of Formula: C10H10O2 The article mentions the following:
Reported herein is the distal γ-C(sp3)-H olefination of ketone derivatives and free carboxylic acids. Fine tuning of a previously reported imino-acid directing group and using the ligand combination of a mono-N-protected amino acid (MPAA) and an electron-deficient 2-pyridone were critical for the γ-C(sp3)-H olefination of ketone substrates. In addition, MPAAs enabled the γ-C(sp3)-H olefination of free carboxylic acids to form diverse six-membered lactones. Besides alkyl carboxylic acids, benzylic C(sp3)-H bonds also could be functionalized to form 3,4-dihydroisocoumarin structures in a single step from 2-Me benzoic acid derivatives The utility of these protocols was demonstrated in large scale reactions and diversification of the γ-C(sp3)-H olefinated products.Benzyl acrylate(cas: 2495-35-4COA of Formula: C10H10O2) was used in this study.
Benzyl acrylate(cas: 2495-35-4) has been used in preparation of high refractive index polyacrylates. Benzyl acrylate is used in the preparation of heptanoic acid benzyl ester. It is used to prepare polybenzylacrylate using azobisisobutyronitrile as initiator.COA of Formula: C10H10O2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics