Palo-Nieto, Carlos; Sau, Abhijit; Jeanneret, Robin; Payard, Pierre-Adrien; Salame, Aude; Martins-Teixeira, Maristela Braga; Carvalho, Ivone; Grimaud, Laurence; Galan, M. Carmen published the artcile< Copper Reactivity Can Be Tuned to Catalyze the Stereoselective Synthesis of 2-Deoxyglycosides from Glycals>, Computed Properties of 4098-06-0, the main research area is glycal deoxy glycoside copper catalyst stereoselective glycosylation disaccharide.
We demonstrate that tuning the reactivity of Cu by the choice of oxidation state and counterion leads to the activation of both “”armed”” and “”disarmed”” type glycals toward direct glycosylation leading to the α-stereoselective synthesis of deoxy-glycosides in good to excellent yields. Mechanistic studies show that CuI is essential for effective catalysis and stereocontrol and that the reaction proceeds through dual activation of both the enol ether as well as the OH nucleophile.
Organic Letters published new progress about Disaccharides Role: SPN (Synthetic Preparation), PREP (Preparation). 4098-06-0 belongs to class esters-buliding-blocks, and the molecular formula is C12H16O7, Computed Properties of 4098-06-0.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics