Maity, Asim; Hyun, Sung-Min; Powers, David C. published the artcile< Oxidase catalysis via aerobically generated hypervalent iodine intermediates>, Reference of 112-63-0, the main research area is hypervalent iodine reagent preparation oxidase catalysis aryl iodide.
The development of sustainable oxidation chem. demands strategies to harness O2 as a terminal oxidant. Oxidase catalysis, in which O2 serves as a chem. oxidant without necessitating incorporation of oxygen into reaction products, would allow diverse substrate functionalization chem. to be coupled to O2 reduction Direct O2 utilization suffers from intrinsic challenges imposed by the triplet ground state of O2 and the disparate electron inventories of four-electron O2 reduction and two-electron substrate oxidation Here, we generate hypervalent iodine reagents-a broadly useful class of selective two-electron oxidants-from O2. This is achieved by intercepting reactive intermediates of aldehyde autoxidation to aerobically generate hypervalent iodine reagents for a broad array of substrate oxidation reactions. The use of aryl iodides as mediators of aerobic oxidation underpins an oxidase catalysis platform that couples substrate oxidation directly to O2 reduction We anticipate that aerobically generated hypervalent iodine reagents will expand the scope of aerobic oxidation chem. in chem. synthesis.
Nature Chemistry published new progress about Aryl iodides Role: RCT (Reactant), RACT (Reactant or Reagent). 112-63-0 belongs to class esters-buliding-blocks, and the molecular formula is C19H34O2, Reference of 112-63-0.
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