Alcohol assisted C-C bond breaking: copper-catalyzed deacetylative α-arylation of β-keto esters and amides was written by Ke, Jie;He, Chuan;Liu, Huiying;Xu, Huan;Lei, Aiwen. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2013.Recommanded Product: 587-88-2 This article mentions the following:
A method of alc.-assisted copper-catalyzed highly selective deacetylative α-arylation of β-keto esters and amides has been demonstrated, which illustrated an efficient example of achieving α-aryl esters and amides. From the synthetic point of view, this arylation protocol is general and practical, representing a simple way to produce α-arylated carbonyl compounds from basic starting materials at low cost. In the experiment, the researchers used many compounds, for example, Ethyl 2-(4-fluorophenyl)acetate (cas: 587-88-2Recommanded Product: 587-88-2).
Ethyl 2-(4-fluorophenyl)acetate (cas: 587-88-2) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Recommanded Product: 587-88-2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics