Metal-Free Oxidative Double C(sp3)-C(sp3) Coupling of 1,3-Dicarbonyl Compounds and N,N-Dimethylanilines was written by Huang, Ling;Cao, Dongdong;Pan, Jie;Fang, Lingjia;Wang, Qianqian;Chen, Dingben;Yang, Jianguo. And the article was included in Advanced Synthesis & Catalysis in 2020.Recommanded Product: Ethyl 3-oxo-3-(m-tolyl)propanoate This article mentions the following:
A metal-free oxidative tandem cross-dehydrogenative coupling of 1,3-dicarbonyl compounds with N,N-dimethylanilines was developed. The reaction afforded two new C(sp3)-C(sp3) bonds in one pot. A broad range of 灏?dicarbonyl compounds and N,N-dimethylanilines were compatible and the desired products were synthesized in moderate to good yields. In the experiment, the researchers used many compounds, for example, Ethyl 3-oxo-3-(m-tolyl)propanoate (cas: 33166-79-9Recommanded Product: Ethyl 3-oxo-3-(m-tolyl)propanoate).
Ethyl 3-oxo-3-(m-tolyl)propanoate (cas: 33166-79-9) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.Recommanded Product: Ethyl 3-oxo-3-(m-tolyl)propanoate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics