Ruthenium-catalyzed benzylic substitution of benzyl esters with stabilized carbon nucleophiles was written by Suzuki, Koki;Tsuji, Hiroaki;Kawatsura, Motoi. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020.Recommanded Product: Diethyl isobutylmalonate This article mentions the following:
A [Cp*RuCl2]2/picolinic acid catalyst system promoted the reaction of 2-naphthylmethyl-2,3,4,5,6-pentafluorobenzoates with a series of stabilized carbon nucleophiles such as malonates, 灏?ketoesters, and diketones to give the corresponding benzylic alkylation products in moderate to high yields. A plausible reaction mechanism that could involve a (锜?benzyl)ruthenium intermediate is proposed. In the experiment, the researchers used many compounds, for example, Diethyl isobutylmalonate (cas: 10203-58-4Recommanded Product: Diethyl isobutylmalonate).
Diethyl isobutylmalonate (cas: 10203-58-4) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Recommanded Product: Diethyl isobutylmalonate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics