Insights into Mechanical, Thermal, and Electrical Properties of Peroxide-Cured Chlorinated Polyethylene/Ethylene Methacrylate Copolymer Blend Vulcanizates was written by Bhagabati, Purabi;Murugesan, Selvakumar. And the article was included in ACS Omega in 2021.Synthetic Route of C73H108O12 This article mentions the following:
This work unveils the effect of chem. modification of compatible elastomer blends based on the chlorinated polyethylene (CPE) and ethylene methacrylate copolymer (EMA) (60:40 ratio) using dicumyl peroxide (DCP). CPE/EMA blend vulcanizates were prepared by varying the DCP concentration from 0.5 to 3.0 wt %. All blend vulcanizates showed significant enhancement in physiomech. properties and thermal stability upon increasing the DCP concentration DCP incorporation also enhanced the compatibility between CPE and EMA rubbers, which was revealed from FTIR data and other tech. properties. Specifically, the vulcanizates with 1.5 wt % DCP showed an enormous improvement in mech. properties and glass transition temperature (Tg) due to various reasons such as cure characteristics, crosslinking densities, co-crosslinking systems, and morphol. features. Uniform distribution of DCP in both the elastomeric phases across their interphases caused co-crosslinking, which increased interphase adhesion in the blend vulcanizates. High interphase adhesion of the blend vulcanizates of 1.5 wt % DCP was directly reflected in its improved mech., thermal, flame retardation properties and enhanced oil resistance and volume resistivity in comparison to pristine CPE/EMA blend vulcanizates. Also, the volume resistivity and oil resistance properties of blend vulcanizates were found to be marginally improved upon increasing the concentration of DCP. In the experiment, the researchers used many compounds, for example, 2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8Synthetic Route of C73H108O12).
2,2-Bis(((3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoyl)oxy)methyl)propane-1,3-diyl bis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propanoate) (cas: 6683-19-8) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Synthetic Route of C73H108O12
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics