Month: January 2023

Oxovanadium(V) and Dioxomolybdenum(VI) Complexes of Amide-Imine Conjugates: Structures, Catalytic and Antitumor Activities was written by Ta, Sabyasachi;Ghosh, Milan;Salam, Noor;Ghosh, Subhasis;Brandao, Paula;Felix, Vitor;Hira, Sumit Kumar;Manna, Partha Pratim;Das, Debasis. And the article was included in ACS Applied Bio Materials in 2019.Computed Properties of C9H10O3 This article mentions the following:

Three new amide-imine conjugates, [(E)-2-hydroxy-N’-((2-hydroxynaphthalen-1-yl)methylene)benzohydrazide] (SALNP), [(E)-N’-(4-(diethylamino)-2-hydroxybenzylidene)-2-hydroxybenzohydrazide](SALSD),and [(E)-N’-(3-ethoxy-4-hydroxybenzylidene)-2-hydroxybenzohydrazide] (SALVN), derived by reacting 2-hydroxybenzohydrazide (SAL) with three different aldehyde, 2-hydroxynaphthaldehyde, 4-(diethylamino)-2-hydroxybenzaldehyde, and 3-ethoxy-4-hydroxybenzaldehyde, resp. Three mononuclear oxovanadium(V) and two μ_oxo-bridged dinuclear molybdenum(VI) complexes were synthesized using SALNP and SALSD. Besides, SALVN was used to prepare oxovanadium(V) and dioxomolybdenum(VI) complexes. All five metal complexes along with three amide-imine conjugates were characterized by single crystal XRD anal. Some of them were explored as catalyst for oxidation of alkyl benzene and styrene. Antitumor activities of the metal complexes along with ligands were studied on Dalton lymphoma (DL) and 2PK3 murine lymphoma cells. In the experiment, the researchers used many compounds, for example, Ethyl 2-hydroxybenzoate (cas: 118-61-6Computed Properties of C9H10O3).

Ethyl 2-hydroxybenzoate (cas: 118-61-6) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Computed Properties of C9H10O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Enantioselectivity switch in asymmetric Michael addition reactions using phosphonium salts was written by Fang, Guosheng;Wang, Hongyu;Zheng, Changwu;Pan, Lu;Zhao, Gang. And the article was included in Organic & Biomolecular Chemistry in 2021.Name: malonic acid dibutyl ester This article mentions the following:

Here,a general method to obtain both enantiomeric products via fine tuning the hydrogen-bonding interactions of phosphonium salts was reported. Amino acid derived phosphonium salts and dipeptide derived phosphonium salts exhibited different properties for controlling the transition state, which could efficiently promote the Michael addition reaction to give opposite configurations of products with high yields and enantioselectivities. Preliminary investigations on the mechanism of the reaction and applications of the products were also performed. In the experiment, the researchers used many compounds, for example, malonic acid dibutyl ester (cas: 1190-39-2Name: malonic acid dibutyl ester).

malonic acid dibutyl ester (cas: 1190-39-2) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Name: malonic acid dibutyl ester

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Chemical Composition and Antioxidant Activity of Thymus ciliatus (Desf.) Benth. Essential Oils of Algeria was written by Souadia, Ahmed. And the article was included in Natural Product Communications in 2022.Safety of (E)-3,7-Dimethylocta-2,6-dien-1-yl acetate This article mentions the following:

The aim of this work was to study the chem. composition and antioxidant activity of essential oils of Thymus ciliatus (Desf.) Benth from middle Algeria obtained from the aerial parts by hydrodistillation using a Clevenger-type apparatus The oil was analyzed by gas chromatog. (GC) and gas chromatog. coupled with mass spectrometry (GC-MS). The antioxidant capacity values of T ciliatus extracts were determined using 2 different and complementary assays: free radical scavenging (2,2-diphenyl-1-picrylhydrazyl [DPPH]) and ferric reducing antioxidant power (FRAP) assays. Six samples of T ciliatus collected in 2019 were used in the study. GC and GC-MS were used to determine the chem. composition of the essential oils. Twenty-five compounds were identified with a percentage of 89.3%-97.7%. The essential oils of T ciliatus were characterized by the presence of myrcene (9.6%-26.9%), p-cymene (7.6%-17.0%), and borneol (13.4%-30.2%) as principal components. In the experiment, the researchers used many compounds, for example, (E)-3,7-Dimethylocta-2,6-dien-1-yl acetate (cas: 105-87-3Safety of (E)-3,7-Dimethylocta-2,6-dien-1-yl acetate).

(E)-3,7-Dimethylocta-2,6-dien-1-yl acetate (cas: 105-87-3) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Safety of (E)-3,7-Dimethylocta-2,6-dien-1-yl acetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Copper-catalyzed cyanoisopropylation of beta-keto esters using azos: synthesis of beta-dicarbonyls bearing an alfa-tertiary nitrile moiety was written by Li, Yanni;Yang, Ruirong;Zhao, Xiaohui;Yao, Yongchao;Yang, Siping;Wu, Qiong;Liang, Deqiang. And the article was included in Synthetic Communications in 2019.Electric Literature of C12H14O3 This article mentions the following:

A copper-catalyzed α-cyanoisopropylation reaction of β-keto esters using azo compounds as cyanoalkylating agents is presented, providing an easy access to β-dicarbonyls containing an α-tertiary nitrile moiety with adjacent tertiary and quaternary carbon centers. It is remarkable because a tremendous steric conflict is involved during reaction. Such nitriles were otherwise unavailable, and the reaction features simple and relatively mild conditions and good functional-group tolerance. In the experiment, the researchers used many compounds, for example, Ethyl 3-oxo-3-(m-tolyl)propanoate (cas: 33166-79-9Electric Literature of C12H14O3).

Ethyl 3-oxo-3-(m-tolyl)propanoate (cas: 33166-79-9) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Electric Literature of C12H14O3

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

DDQ-Catalyzed Direct C(sp³)-H Amination of Alkylheteroarenes: Synthesis of Biheteroarenes under Aerobic and Metal-Free Conditions was written by Song, Chunlan;Dong, Xin;Yi, Hong;Chiang, Chien-Wei;Lei, Aiwen. And the article was included in ACS Catalysis in 2018.Recommanded Product: Methyl 2-thienylacetate This article mentions the following:

A strategy for oxidative Csp³-H/N-H cross-coupling is presented. This reaction successfully utilizes 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) and tert-Bu nitrite (TBN) as co-catalysts to construct the biomedical applicable biheteroarenes under aerobic conditions. Notably, this amination reaction is successful with a wide range of alkylheteroarenes and could be used as a functionalization tactic for pharmaceutical research and other areas. Furthermore, preliminary mechanistic studies indicate that the C-N bond formation proceeds through the nucleophilic attack of azole to the carbon cation. In the experiment, the researchers used many compounds, for example, Methyl 2-thienylacetate (cas: 19432-68-9Recommanded Product: Methyl 2-thienylacetate).

Methyl 2-thienylacetate (cas: 19432-68-9) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Recommanded Product: Methyl 2-thienylacetate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Reduction effects of solar radiation, mechanical tension, and soil burial on phthalate esters concentrations in plastic film and soils was written by Wang, Dong;Xi, Yue;Shi, Xiao-Yan;Han, Ya-Nan;Zhang, Ning;Ahmad, Farhan;Li, Feng-Min. And the article was included in Science of the Total Environment in 2021.Safety of Dicyclohexyl phthalate This article mentions the following:

Phthalate esters (PAEs) are potentially dangerous chems. in plastic film mulched fields; however, few studies have investigated how to reduce their concentrations in plastic film and soil. In this study, the effects of solar radiation, mech. tension, and soil burial on PAEs concentrations in polyethylene (PE) film and degradable film were investigated, and the half-lives of di-Bu phthalate (DBP) and di(2-ethylhexyl) phthalate (DEHP) in soil also studied. PAEs concentrations in polyethylene films were about twice those in the degradable films; however, PAEs concentrations in all exptl. films were similar after 1-yr of field exposure. Mech. tension had no effect on the PAEs concentrations of polyethylene films, but increased the detected concentrations of PAEs in degradable films by 34%-120%. After 4-years of burial, the PAEs concentrations in films decreased by 79.2%-98.0%, and mech. tension promoted the reductions However, there was little difference in PAEs concentrations between the buried soils with and without films, indicating the released PAEs reduced quickly in soil. Also, the half-lives of DBP and DEHP were 2.4-4.6 days and 18.5-41.4 days, resp. Overall, the results presented herein provide reasonable approaches to reduce the concentrations of PAEs in plastic films and soils. In the experiment, the researchers used many compounds, for example, Dicyclohexyl phthalate (cas: 84-61-7Safety of Dicyclohexyl phthalate).

Dicyclohexyl phthalate (cas: 84-61-7) belongs to esters. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Safety of Dicyclohexyl phthalate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Identification of Cytotoxic Flavor Chemicals in Top-Selling Electronic Cigarette Refill Fluids was written by Hua, My;Omaiye, Esther E.;Luo, Wentai;McWhirter, Kevin J.;Pankow, James F.;Talbot, Prue. And the article was included in Scientific Reports in 2019.HPLC of Formula: 659-70-1 This article mentions the following:

We identified the most popular electronic cigarette (EC) refill fluids using an Internet survey and local and online sales information, quantified their flavor chems., and evaluated cytotoxicities of the fluids and flavor chems. “Berries/Fruits/Citrus” was the most popular EC refill fluid flavor category. Twenty popular EC refill fluids were purchased from local shops, and the ingredient flavor chems. were identified and quantified by gas chromatog.-mass spectrometry. Total flavor chem. concentrations ranged from 0.6 to 27.9 mg/mL, and in 95% of the fluids, total flavor concentration was greater than nicotine concentration The 20 most popular refill fluids contained 99 quantifiable flavor chems.; each refill fluid contained 22 to 47 flavor chems., most being esters. Some chems. were found frequently, and several were present in most products. At a 1% concentration, 80% of the refill fluids were cytotoxic in the MTT assay. Six pure standards of the flavor chems. found at the highest concentrations in the two most cytotoxic refill fluids were effective in the MTT assay, and ethyl maltol, which was in over 50% of the products, was the most cytotoxic. These data show that the cytotoxicity of some popular refill fluids can be attributed to their high concentrations of flavor chems. In the experiment, the researchers used many compounds, for example, Isopentyl 3-methylbutanoate (cas: 659-70-1HPLC of Formula: 659-70-1).

Isopentyl 3-methylbutanoate (cas: 659-70-1) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.HPLC of Formula: 659-70-1

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Highly enantioselective desymmetrization of anhydrides by carbon nucleophiles: reactions of Grignard reagents in the presence of (-)-sparteine was written by Shintani, Ryo;Fu, Gregory C.. And the article was included in Angewandte Chemie, International Edition in 2002.Reference of 10203-58-4 This article mentions the following:

Where other common chiral ligands failed, (-)-sparteine can be employed to form complexes with Grignard reagents. These chirally modified reagents desymmetrize a range of anhydrides with good enantioselectivity (up to 92% ee). Whereas (-)-sparteine is well known to form complexes with organolithium reagents and to induce excellent enantioselection in their reactions with electrophiles, (-)-sparteine-controlled asym. processes that involve Grignard reagents are rare. In the experiment, the researchers used many compounds, for example, Diethyl isobutylmalonate (cas: 10203-58-4Reference of 10203-58-4).

Diethyl isobutylmalonate (cas: 10203-58-4) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Reference of 10203-58-4

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Development of a dual MOS electronic nose/camera system for improving fruit ripeness classification was written by Chen, Li-Ying;Wu, Cheng-Chun;Chou, Ting-I.;Chiu, Shih-Wen;Tang, Kea-Tiong. And the article was included in Sensors in 2018.Electric Literature of C10H20O2 This article mentions the following:

Electronic nose (E-nose) systems have become popular in food and fruit quality evaluation because of their rapid and repeatable availability and robustness. In this paper, we propose an E-nose system that has potential as a non-destructive system for monitoring variation in the volatile organic compounds produced by fruit during the maturing process. In addition to the E-nose system, we also propose a camera system to monitor the peel color of fruit as another feature for identification. By incorporating E-nose and camera systems together, we propose a non-destructive solution for fruit maturity monitoring. The dual E-nose/camera system presents the best Fisher class separability measure and shows a perfect classification of the four maturity stages of a banana: Unripe, half-ripe, fully ripe, and overripe. In the experiment, the researchers used many compounds, for example, Isopentyl 3-methylbutanoate (cas: 659-70-1Electric Literature of C10H20O2).

Isopentyl 3-methylbutanoate (cas: 659-70-1) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Electric Literature of C10H20O2

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics

Differential volatile organic compounds signatures of apple juices from Madeira Island according to variety and geographical origin was written by Medina, Sonia;Perestrelo, Rosa;Santos, Rui;Pereira, Regina;Camara, Jose S.. And the article was included in Microchemical Journal in 2019.Electric Literature of C6H12O2 This article mentions the following:

One of the main food authenticity issues is related to products�false labeling concerning their variety or geog. origin. For this reason, the aim of this study was to establish distinctive characteristics for the discrimination of apple juices according to regional varieties (Rijo, Verde, Ribeiro and Azedo) and geog. origin (Prazeres and Santo da Serra (Madeira Island)) on the basis of their volatile pattern by headspace solid-phase microextraction combined with gas chromatog. mass spectrometry (HS-SPME/GC-MS) combined with chemometric tools. The results obtained revealed a perfect discrimination between the different apple varieties, with Rijo apple juices as samples with the major relative concentration of ethanol, Et butanoate, Et 2-methylbutanoate and Et hexanoate. Moreover, this study allowed a geog. origin-based classification of Azedo apple juices, highlighting Et acetate, 2-methyl-1-propanol, Et hexanoate, and toluene (described for the first time in apple juices) as discriminatory features. This study demonstrated that volatile organic compounds (VOCs) could serve as authenticity indicators to verify variety and geog. origin of apple juices, providing local producers multiple benefits and legal protection against misuse of the products. In the experiment, the researchers used many compounds, for example, Methyl2-methylbutyrate (cas: 868-57-5Electric Literature of C6H12O2).

Methyl2-methylbutyrate (cas: 868-57-5) belongs to esters. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Electric Literature of C6H12O2

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics