Zhou, Wei published the artcileTetrachlorophthalimides as Organocatalytic Acceptors for Electron Donor-Acceptor Complex Photoactivation, Computed Properties of 624-49-7, the publication is Journal of the American Chemical Society (2022), 144(20), 8914-8919, database is CAplus and MEDLINE.
Herein, the available electron-poor tetrachlorophthalimides I (R = Ph, 2,4,6-trimethylphenyl) can act as effective organocatalytic acceptors to trigger the formation of EDA complexes with a variety of radical precursors not amenable to previous catalytic methods. Excitation with visible light generates carbon radicals under mild conditions. The versatility of this EDA complex catalytic platform allowed to develop mechanistically distinct radical reactions, including in combination with a cobalt-based catalytic system. Quantum yield measurements established that a closed catalytic cycle is operational, which hints at the ability of tetrachlorophthalimides I to readily turn over and govern each catalytic cycle.
Journal of the American Chemical Society published new progress about 624-49-7. 624-49-7 belongs to esters-buliding-blocks, auxiliary class Inhibitor,Natural product, name is Dimethyl fumarate, and the molecular formula is C19H34ClN, Computed Properties of 624-49-7.
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