Wang, Weichao published the artcileDetermining Roles of Cu0 in the Chemosynthesis of Diols via Condensed Diester Hydrogenation on Cu/SiO2 Catalyst, Category: esters-buliding-blocks, the publication is ChemCatChem (2020), 12(15), 3849-3852, database is CAplus.
Copper-based catalyst was applied in the condensed diester hydrogenation with unexpected high selectivity (∼100%) to 1,6-hexanediol. On basis of the mass transfer anal. and kinetics results, the reaction rate of the condensed diester hydrogenation was deduced to be controlled by the activation of hydrogen on Cu0 sites, which was further demonstrated by the correlations between the catalytic activity and different copper species. Importantly, this catalysis mechanism is different with that of gas-phase diester hydrogenation, which is generally determined by the adsorption of ester on Cu+ species.
ChemCatChem published new progress about 627-93-0. 627-93-0 belongs to esters-buliding-blocks, auxiliary class Ploymers, name is Dimethyl adipate, and the molecular formula is C8H7ClO3, Category: esters-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics