Meng, Qing-Yuan published the artcileCarboxylation of Aromatic and Aliphatic Bromides and Triflates with CO2 by Dual Visible-Light-Nickel Catalysis, Application In Synthesis of 1877-71-0, the publication is Angewandte Chemie, International Edition (2017), 56(43), 13426-13430, database is CAplus and MEDLINE.
The authors report the efficient carboxylation of bromides and triflates with K2CO3 as the source of CO2 in the presence of an organic photocatalyst in combination with a nickel complex under visible light irradiation at room temperature The reaction is compatible with a variety of functional groups and was successfully applied to the synthesis and derivatization of biol. active mols. In particular, the carboxylation of unactivated cyclic alkyl bromides proceeded well with the authors’ protocol, thus extending the scope of this transformation. Spectroscopic and spectroelectrochem. studies indicated the generation of a Ni0 species as a catalytic reactive intermediate.
Angewandte Chemie, International Edition published new progress about 1877-71-0. 1877-71-0 belongs to esters-buliding-blocks, auxiliary class Carboxylic acid,Benzene,Ester, name is 3-(Methoxycarbonyl)benzoic acid, and the molecular formula is C9H8O4, Application In Synthesis of 1877-71-0.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics