Kongkaew, A. published the artcileEffects of reaction conditions on poly(methyl methacrylate) polymerized by living radical polymerization with iniferter, Safety of Benzyl diethylcarbamodithioate, the publication is Journal of Applied Polymer Science (2000), 75(7), 938-944, database is CAplus.
Living radical polymerization of Me methacrylate (MMA) through the use of benzyl diethyldithiocarbamate (BDC) was studied. The aim was to investigate the role of the concentration, BDC-to-MMA mol ratio, and reaction time upon the mol. weight, polydispersity, and conversion of the product. It was found that the mol. weight and the conversion increase with increase of the concentration at the expense of low polydispersity. The reaction time also played a significant role, especially at a relatively long reaction time where mol. weight, polydispersity, and conversion increased with increasing reaction time. In terms of the mol ratio effect, it was found that there was a critical mol ratio for maximum conversion. The results indicate that the kinetics of polymerization of MMA through the use of a BDC iniferter is different from that in the presence of a conventional initiator.
Journal of Applied Polymer Science published new progress about 3052-61-7. 3052-61-7 belongs to esters-buliding-blocks, auxiliary class Amine,Benzene,Amide, name is Benzyl diethylcarbamodithioate, and the molecular formula is C12H17NS2, Safety of Benzyl diethylcarbamodithioate.
Referemce:
https://en.wikipedia.org/wiki/Ester,
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