Chen, Haifeng published the artcileFormation of allylated quaternary carbon centers via C-O/C-O bond fragmentation of oxalates and allyl carbonates, Computed Properties of 5205-11-8, the publication is Chemical Communications (Cambridge, United Kingdom) (2020), 56(3), 454-457, database is CAplus and MEDLINE.
Disclosed herein emphasizes Fe-promoted cross-electrophile allylation of tertiary alkyl oxalates with allyl carbonates that generates all C(sp3)-quaternary centers. The reaction involves fragmentation of tertiary alkyl oxalate C-O bonds to give tertiary alkyl radical intermediates, addition of the radicals to less hindered alkene terminals, and subsequent cleavage of the allyl C-O bonds. Allylation with 2-aryl substituted allyl carbonates was mediated by Zn/MgCl2, and Fe was used to promote the radical addition efficiency. By introduction of activated alkenes, a three-component radical cascade reaction took place.
Chemical Communications (Cambridge, United Kingdom) published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H14O2, Computed Properties of 5205-11-8.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics