Bovin, N. V.’s team published research in Bioorganicheskaya Khimiya in 12 | CAS: 10378-06-0

Bioorganicheskaya Khimiya published new progress about 10378-06-0. 10378-06-0 belongs to esters-buliding-blocks, auxiliary class Other Aliphatic Heterocyclic,Chiral,Ester,Inhibitor,Inhibitor, name is (3aR,5R,6R,7R,7aR)-5-(Acetoxymethyl)-2-methyl-5,6,7,7a-tetrahydro-3aH-pyrano[3,2-d]oxazole-6,7-diyl diacetate, and the molecular formula is C14H19NO8, Safety of (3aR,5R,6R,7R,7aR)-5-(Acetoxymethyl)-2-methyl-5,6,7,7a-tetrahydro-3aH-pyrano[3,2-d]oxazole-6,7-diyl diacetate.

Bovin, N. V. published the artcileIsomerization of (trifluoroacetamido)propyl 2-acetamido-2-deoxy-β-D-galactopyranoside into an α-anomer. A facile synthesis of artificial T-antigen, Safety of (3aR,5R,6R,7R,7aR)-5-(Acetoxymethyl)-2-methyl-5,6,7,7a-tetrahydro-3aH-pyrano[3,2-d]oxazole-6,7-diyl diacetate, the publication is Bioorganicheskaya Khimiya (1986), 12(4), 533-8, database is CAplus and MEDLINE.

β-Glycoside I [R = O(CH2)3NHAc, R1 = H], prepared by glycosidation of I (R = H, R1 = Cl) with HO(CH2)3NHAc in the presence of Hg(CN)2, was isomerized by BF3.Et2O to give 50-60% α-anomer I [R = H, R1 = O(CH2)3NHAc] (II) and oxazoline III. α-Anomer II was converted to benzylidene derivative IV (R = H) which was glycosidated by acetobromogalactose to give 50% IV (R = 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl), followed by deacetylation to give bioside V, the precursor for artificial T-antigen.

Bioorganicheskaya Khimiya published new progress about 10378-06-0. 10378-06-0 belongs to esters-buliding-blocks, auxiliary class Other Aliphatic Heterocyclic,Chiral,Ester,Inhibitor,Inhibitor, name is (3aR,5R,6R,7R,7aR)-5-(Acetoxymethyl)-2-methyl-5,6,7,7a-tetrahydro-3aH-pyrano[3,2-d]oxazole-6,7-diyl diacetate, and the molecular formula is C14H19NO8, Safety of (3aR,5R,6R,7R,7aR)-5-(Acetoxymethyl)-2-methyl-5,6,7,7a-tetrahydro-3aH-pyrano[3,2-d]oxazole-6,7-diyl diacetate.

Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics